Through the looking glass: artificial ‘molecules’ open door to ultrafast devices

Polaritons are quantum particles that consist of a photon and an exciton, another quasiparticle, combining light and matter in a curious union that opens up a multitude of possibilities in next-generation devices.

The researchers have shown that geometrically coupled polariton condensates, which appear in semiconductor devices, are capable of simulating molecules with various properties.

Ordinary molecules are groups of atoms bound together with molecular bonds, and their physical properties differ from those of their constituent atoms quite drastically: consider the water molecule, H₂O, and elemental hydrogen and oxygen.

“In our work, we show that clusters of interacting polaritonic and photonic condensates can form a range of exotic and entirely distinct entities – ‘molecules’ – that can be manipulated artificially,” said first author Alexander Johnston, from Cambridge Department of Applied Mathematics and Theoretical Physics. “These artificial molecules possess new energy states, optical properties, and vibrational modes from those of the condensates comprising them.”

Johnston and his colleagues – Kirill Kalinin from DAMTP and Professor Natalia Berloff, who holds joint positions at Cambridge and Skoltech – were running numerical simulations of two, three, and four interacting polariton condensates, when they noticed some curious asymmetric stationary states in which not all of the condensates have the same density in their ground state.

“Upon further investigation, we found that such states came in a wide variety of different forms, which could be controlled by manipulating certain physical parameters of the system,” said Johnston. “This led us to propose such phenomena as artificial polariton molecules and to investigate their potential uses in quantum information systems.”

In particular, the team focused on an ‘asymmetric dyad’, which consists of two interacting condensates with unequal occupations. When two of those dyads are combined into a tetrad structure, the latter is, in some sense, analogous to a homonuclear molecule – for instance, to molecular hydrogen H₂. Furthermore, artificial polariton molecules can also form more elaborate structures, which could be thought of as artificial polariton compounds.

“There is nothing preventing more complex structures from being created,” said Johnston. “We’ve found that there is a wide range of exotic, asymmetric states possible in tetrad configurations. In some of these, all condensates have different densities, despite all of the couplings being of equal strength, inviting an analogy with chemical compounds.”

In specific tetrad structures, each asymmetric dyad can be viewed as an individual ‘spin,’ defined by the orientation of the density asymmetry. This has interesting consequences for the system’s degrees of freedom, or the independent physical parameters required to define states. The spins introduce a separate degree of freedom, in addition to the continuous degrees of freedom given by the condensate phases.

The relative orientation of each of the dyads can be controlled by varying the coupling strength between them. Since quantum information sem.

“In addition, we have discovered a plethora of exotic asymmetric states in triad and tetrad systems,” said Berloff. “It is possible to seamlessly transition between such states simply by varying the pumping strength used to form the condensates. This property suggests that such states could form the basis of a polaritonic multi-valued logic system, which could enable the development of polaritonic devices that dissipate significantly less power than traditional methods and, potentially, operate orders of magnitude faster.”

Reference:
Alexander Johnston, Kirill P. Kalinin, and Natalia G. Berloff. ‘Artificial polariton molecules.’ Physical Review Letters B (2021). DOI: 10.1103/PhysRevB.103.L060507

Adapted from a Skoltech press release.